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引用本文:   袁小雪, 江阳, 杨长晓, 谢碧俊, 雍莉, 胡彬, 刘滔. 快速溶剂提取-高效液相色谱法测定PM2.5中16种多环芳烃. 分析化学, 2017, 45(11): 1641-1647. doi:  10.11895/j.issn.0253-3820.170262 [复制]

Citation:   YUAN Xiao-Xue, JIANG Yang, YANG Chang-Xiao, XIE Bi-Jun, YONG Li, HU Bin, LIU Tao. Determination of 16 Kinds of Polycyclic Aromatic Hydrocarbons in Atmospheric Fine Particles by Accelerated Solvent Extraction Coupled with High Performance Liquid Chromatography. Chinese Journal of Analytical Chemistry, 2017, 45(11): 1641-1647. doi: 10.11895/j.issn.0253-3820.170262 [复制]

快速溶剂提取-高效液相色谱法测定PM2.5中16种多环芳烃

收稿日期: 2017-04-26

接受日期: 2017-09-04

出版日期: 2017-11-20

Determination of 16 Kinds of Polycyclic Aromatic Hydrocarbons in Atmospheric Fine Particles by Accelerated Solvent Extraction Coupled with High Performance Liquid Chromatography

Received Date:  2017-04-26

Accepted Date:  2017-09-04

Published Date:  2017-11-20

建立大气细颗粒物(PM2.5)中16种多环芳烃(PAHs)的快速溶剂提取-直接进样-高效液相色谱测定方法。PM2.5经玻璃纤维滤膜收集,采样后的滤膜直接用乙腈经快速溶剂萃取仪提取,以乙腈和水作为流动相,提取液通过ZORBAX Eclipse PAH液相色谱柱分离,紫外串联荧光检测器检测。16种PAHs分离效果良好,在0.025~5.000μg/mL范围内线性相关系数r≥0.9998,方法加标回收率为78.3%~113.2%,相对标准偏差为0.5%~9.5%,检出限为0.007~0.062 ng/m3。本方法操作简便、快速、准确、灵敏,适于PM2.5中16种PAHs的同时测定。

关键词:   快速溶剂提取, PM2.5, 多环芳烃, 高效液相色谱法
Key words:   Accelerated solvent extraction, Atmospheric fine particles, Polycyclic aromatic hydrocarbons, High performance liquid chromatography
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目录

快速溶剂提取-高效液相色谱法测定PM2.5中16种多环芳烃

袁小雪, 江阳, 杨长晓, 谢碧俊, 雍莉, 胡彬, 刘滔

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