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引用本文:   杨琪, 苗艳明, 李艳, 孙晓杰, 闫桂琴. 基于室温磷光量子点/硼酸基联吡啶盐纳米复合材料检测果糖. 分析化学, 2017, 45(11): 1606-1612. doi:  10.11895/j.issn.0253-3820.170355 [复制]

Citation:   YANG Qi, MIAO Yan-Ming, LI Yan, SUN Xiao-Jie, YAN Gui-Qin. Synthesis of Quantum Dot/Boronic Acid-substituted Bipyridinium Salt Nanohybrids as Room-temperature Phosphorescence Probe for Fructose Detection. Chinese Journal of Analytical Chemistry, 2017, 45(11): 1606-1612. doi: 10.11895/j.issn.0253-3820.170355 [复制]

基于室温磷光量子点/硼酸基联吡啶盐纳米复合材料检测果糖

通讯作者:  苗艳明, mym8207@126.com

收稿日期: 2017-06-05

接受日期: 2017-09-04

出版日期: 2017-11-20

基金项目: 本文系山西省青年科技研究基金(No.201601D021109)和山西省重点化学优势学科建设项目(No.912019)资助

Synthesis of Quantum Dot/Boronic Acid-substituted Bipyridinium Salt Nanohybrids as Room-temperature Phosphorescence Probe for Fructose Detection

Corresponding author:  MIAO Yan-Ming, mym8207@126.com

Received Date:  2017-06-05

Accepted Date:  2017-09-04

Published Date:  2017-11-20

以Mn掺杂的ZnS(Mn-ZnS)室温磷光(RTP)量子点的磷光为信号,以2-溴甲基苯硼酸与4,4'-联吡啶为原料合成的硼酸基联吡啶盐(BBV)为受体,带负电的量子点与带正电BBV通过静电作用形成Mn-ZnS/BBV纳米复合材料,Mn-ZnS量子点磷光猝灭,加入果糖,BBV与果糖形成阴离子硼酸酯,降低了对量子点猝灭效率,RTP恢复。考察了时间、pH值对Mn掺杂的ZnS QDs/BBV纳米复合材料磷光强度的影响,在最优条件下,此传感器检测果糖的线性范围为0.05-1.00 mmol/L,检出限为0.01 mmol/L,相关系数r为0.99。本磷光分析法简便快速、灵敏度高,有望应用于食品、医药行业中果糖含量的检测分析。

关键词:   量子点, 室温磷光, 硼酸基联吡啶盐, 果糖
Key words:   Quantum dots, Room-temperature phosphorescence, Boronic acid-substituted bipyridinium salt, Fructose
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基于室温磷光量子点/硼酸基联吡啶盐纳米复合材料检测果糖

杨琪, 苗艳明, 李艳, 孙晓杰, 闫桂琴

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