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引用本文:   钟燕辉, 卢晓钿, 黄婉婷, 张润坤, 李攻科. 循环化学发光快速区分醇类化合物. 分析化学, 2017, 45(11): 1628-1634. doi:  10.11895/j.issn.0253-3820.171010 [复制]

Citation:   ZHONG Yan-Hui, LU Xiao-Tian, HUANG Wan-Ting, ZHANG Run-Kun, LI Gong-Ke. Rapid Identification of Alcohol Compounds by Cyclic Chemiluminescence. Chinese Journal of Analytical Chemistry, 2017, 45(11): 1628-1634. doi: 10.11895/j.issn.0253-3820.171010 [复制]

循环化学发光快速区分醇类化合物

通讯作者:  张润坤, zhangrk5@mail.sysu.edu.cn; 李攻科, cesgkl@mail.sysu.edu.cn

收稿日期: 2017-06-16

接受日期: 2017-09-07

出版日期: 2017-11-20

基金项目: 本文系国家自然科学基金(Nos.21475153、21605163、21675178)和高校基本科研业务费青年教师培育项目(No.31000-31610743)资助

Rapid Identification of Alcohol Compounds by Cyclic Chemiluminescence

Corresponding author:  ZHANG Run-Kun, zhangrk5@mail.sysu.edu.cn; LI Gong-Ke, cesgkl@mail.sysu.edu.cn

Received Date:  2017-06-16

Accepted Date:  2017-09-07

Published Date:  2017-11-20

Fund Project:  This work was supported by the National Natural Science Foundation of China (Nos. 21475153, 21605163, 21675178) and the Cultivation Project of Young Teacher in University (No. 31000-31610743)

以纳米氧化镁为催化剂构建了循环化学发光(Cyclic chemiluminescence,CCL)系统,以醇类化合物为研究对象,研究了反应物浓度、反应温度和检测波长对CCL分析的影响。结果表明,CCL检测信号满足一级指数衰减规律,每个反应均对应一个描述其信号变化规律的指数方程,其初变量A与反应物浓度呈线性关系,衰减系数k是与反应物浓度无关的特征常数。以异丁醇为例,其A值与浓度在0.89~14.24 mg/L之间呈良好的线性关系,线性范围内的k值平均值为32.0,RSD=2.2%,可根据k值进行定性分析,根据A值进行定量分析。采用此系统分析了8种醇类化合物,发现其k值存在显著差异,如正丁醇、异丁醇、叔丁醇的k值分别为27.2±0.2、32.0±0.8及19.5±0.1,据此提出了一种快速区分醇类同系物及结构异构体的新方法。

关键词:   循环化学发光, 催化发光, 氧化镁, 醇类
Key words:   Cyclic chemiluminescence, Cataluminescence, Magnesium oxide, Alcohols
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循环化学发光快速区分醇类化合物

钟燕辉, 卢晓钿, 黄婉婷, 张润坤, 李攻科

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