会员登陆: 用户名:  密码: 验证码:
首页 杂志概况 投稿须知 在线投稿 在线阅读 征订启事 广告服务 行业资讯 企业动态 资料中心  专访报道 会展信息 ENGLISH

引用本文:   高成耀, 佟建华, 边超, 孙楫舟, 李洋, 王晋芬, 龚顺, 惠允, 徐钰豪, 王晓青, 谢虎成, 夏善红. 锌、镉、铅离子在原位铋修饰掺硼金刚石薄膜电极上的传感分析. 分析化学, 2018, 46(2): 217-224. doi:  10.11895/j.issn.0253-3820.171026 [复制]

Citation:   GAO Cheng-Yao, TONG Jian-Hua, BIAN Chao, SUN Ji-Zhou, LI Yang, WANG Jin-Fen, GONG Shun, HUI Yun, XU Yu-Hao, WANG Xiao-Qing, XIE Hu-Cheng, XIA Shan-Hong. Determination of Trace Zn, Cd and Pb Metal Ions Using In-situ Bismuth-modified Boron Doped Diamond Electrode. Chinese Journal of Analytical Chemistry, 2018, 46(2): 217-224. doi: 10.11895/j.issn.0253-3820.171026 [复制]

锌、镉、铅离子在原位铋修饰掺硼金刚石薄膜电极上的传感分析

通讯作者:  夏善红, shxia@mail.ie.ac.cn

收稿日期: 2017-06-21

接受日期: 2017-11-06

出版日期: 2018-02-01

基金项目: 本文系国家重点基础研究发展(973)计划项目(No.2015CB352100)、国家自然科学基金项目(No.61306010)和河北省自然科学基金项目(No.E2014507012)资助

Determination of Trace Zn, Cd and Pb Metal Ions Using In-situ Bismuth-modified Boron Doped Diamond Electrode

Corresponding author:  XIA Shan-Hong, shxia@mail.ie.ac.cn

Received Date:  2017-06-21

Accepted Date:  2017-11-06

Published Date:  2018-02-01

以原位铋修饰掺硼金刚石薄膜电极为传感电极,利用阳极溶出伏安法对重金属离子Zn2+、Cd2+、Pb2+进行同时检测分析。原位铋修饰掺硼金刚石薄膜电极可有效提高Zn2+、Cd2+、Pb2+的溶出峰值电流。考察了pH值、扫描方式、电极硼掺杂浓度、富集电位等参数对检测分析的影响。在优化的实验条件下,原位铋修饰BDD电极对Zn2+、Cd2+、Pb2+传感分析具有良好的特性,在10~300 μg/L浓度范围内具有良好的线性度和重复性,检出限分别为0.56、0.32和0.75 μg/L(S/N=3)。干扰实验结果表明,3种重金属的相互干扰较小,除Cu2+外,水中常见离子对测定干扰较小。实际水样中,3种离子的回收率为92.0%~114.0%。

关键词:   掺硼金刚石薄膜电极, 阳极溶出伏安法, 重金属离子, 同时检测, 电化学传感器
Key words:   Boron doped diamond thin film electrode, Anodic stripping voltammetry, Heavy metal ions, Simultaneous detection, Electrochemical sensor
[1]

Li Z, Ma Z, van der Kuijp T J, Yuan Z, Huang L. Sci. Total Environ., 2014, 468: 843-853

[2]

Sun Q, Wang J, Tang M, Huang L, Zhang Z, Liu C, Lu X, Hunter K W, Chen G. Anal. Chem., 2017, 89(9): 5024-5029

[3]

Quiroa Montalvan C M, Gomez Pineda L E, Alvarez Contreras L, Valdez R, Arjona N, Oropeza-Guzman M T. J. Electrochem. Soc., 2017, 164(6): B304-B313. doi: 10.1149/2.0231707jes

[4]

Jiokeng S L Z, Dongmo L M, Ymele E, Ngameni E, Tonle I K. Sens. Actuators B, 2017, 242: 1027-1034. doi: 10.1016/j.snb.2016.09.150

[5]

Allafchian A, Mirahmadi Zare S Z, Gholamian M. IEEE Sens. J., 2017, 17(9): 2856-2862. doi: 10.1109/JSEN.2017.2680450

[6]

TANG Feng-Jie, ZHANG Feng, JIN Qing-Hui, ZHAO Jian-Long. Chinese J. Anal. Chem., 2013, 41(2): 278-282

唐逢杰, 张凤, 金庆辉, 赵建龙. 分析化学, 2013, 41(2): 278-282

[7]

Rodrigues J A, Rodrigues C M, Almeida P J, Valente I M, Goncalves L M, Compton R G, Barros A A. Anal. Chim. Acta, 2011, 701(2): 152-156. doi: 10.1016/j.aca.2011.05.031

[8]

Ensafi A A, Nazari Z, Fritsch I. Electroanalysis, 2010, 22(21): 2551-2557. doi: 10.1002/elan.v22:21

[9]

GAO Cheng-Yao, CHANG Ming, LI Xiao-Wei, LI Cui-Ping. Progess in Chemistry, 2011, 23(5): 951-962

高成耀, 常明, 李晓伟, 李翠平. 化学进展, 2011, 23(5): 951-962

[10]

Ivandini T A, Wicaksono W P, Saepudin E, Rismetov B, Einaga Y. Talanta, 2015, 134: 136-143. doi: 10.1016/j.talanta.2014.11.010

[11]

Chaiyo S, Chailapakul O, Siangproh W. Anal. Chim. Acta, 2014, 852: 55-62. doi: 10.1016/j.aca.2014.09.011

[12]

El Tall O, Jaffrezic Renault N, Sigaud M, Vittori O. Electroanalysis, 2007, 19(11): 1152-1159. doi: 10.1002/(ISSN)1521-4109

[13]

McGaw E A, Swain G M. Anal. Chim. Acta, 2006, 575(2): 180-189. doi: 10.1016/j.aca.2006.05.094

[14]

Culkova E, Svorc L u, Tomcik P, Durdiak J, Rievaj M, Bustin D, Breseher R, Lokaj J. Pol. J. Environ. Stud., 2013, 22(5): 1317-1323

[15]

Zhang T, Li C, Mao B, An Y. Ionics, 2015, 21(6): 1761-1769. doi: 10.1007/s11581-014-1350-6

[16]

Guo Y, Huang N, Yang B, Wang C, Zhuang H, Tian Q, Zhai Z, Liu L, Jiang X. Sens. Actuators B, 2016, 231: 194-202. doi: 10.1016/j.snb.2016.02.098

[17]

Honorio G G, Azevedo G C, Costa Matos M A, Leal de Oliveira M A, Matos R C. Food Control, 2014, 36(1): 42-48. doi: 10.1016/j.foodcont.2013.08.004

[18]

Chooto P, Wararatananurak P, Innuphat C. Scienceasia, 2010, 36(2): 150-156. doi: 10.2306/scienceasia1513-1874.2010.36.150

[19]

Wang J, Lu J M, Hocevar S B, Ogorevc B. Electroanalysis, 2001, 13(1): 13-16. doi: 10.1002/(ISSN)1521-4109

[20]

Wang J, Lu J M, Hocevar S B, Farias P A M, Ogorevc B. Anal. Chem., 2000, 72(14): 3218-3222. doi: 10.1021/ac000108x

[21]

Xu H, Zeng L, Huang D, Man Y, Jin L. Food Chem., 2008, 109(4): 834-839. doi: 10.1016/j.foodchem.2007.12.065

[22]

LI Dong-Yue, JIA Jian-Bo, WANG Jian-Guo. Chinese J.Anal. Chem., 2012, 40(2): 321-327

李冬月, 郏建波, 王建国. 分析化学, 2012, 40(2): 321-327

[23]

Azevedo A F, De Barros R C M, Serrano S H P, Ferreira N G. Surf. Coat. Tech., 2006, 200(20-21): 5973-5977. doi: 10.1016/j.surfcoat.2005.09.012

[24]

Malard L M, Pimenta M A, Dresselhaus G, Dresselhaus M S. Phys. Rep., 2009, 473(5-6): 51-87. doi: 10.1016/j.physrep.2009.02.003

[25]

Bard A J, Faulkner L R. Electrochemical Methods:Fundamentals and Applications, 2nd ed. New York:Wiley Interscience, 2001, : 231-

[26]

Kruusma J, Banks C E, Compton R G. Anal. Bioanal. Chem., 2004, 379(4): 700-706

[27]

Karolina Schwarzová-Pecková J V, Jirí Barek, Ivana Sloufová. Electrochim. Acta, 2017, 243: 170-182. doi: 10.1016/j.electacta.2017.05.006

[28]

Din S H, Shah M A, Sheikh N A, Najar K A, Ramasubramanian K, Balaji S, Rao M S R. Bull. Mater Sci., 2016, 39(7): 1753-1761. doi: 10.1007/s12034-016-1311-y

[29]

Crowley K, Cassidy J. Electroanalysis, 2002, 14(15-16): 1077-1082. doi: 10.1002/1521-4109(200208)14:15/16<1077::AID-ELAN1077>3.0.CO;2-3

计量
  • PDF下载量(6)
  • 文章访问量(134)
  • HTML全文浏览量(1)

目录

锌、镉、铅离子在原位铋修饰掺硼金刚石薄膜电极上的传感分析

高成耀, 佟建华, 边超, 孙楫舟, 李洋, 王晋芬, 龚顺, 惠允, 徐钰豪, 王晓青, 谢虎成, 夏善红

Figures and Tables